Contact Information

Author
  • Donna Narsavage-Heald
  • Assoc. Professor
  • Chemistry and Biochemistry
  • Siena College
  • Loudonville, NY 12211
Email
Phone
(518) 782 - 6707
Website

Thermal Polyaspartate as a Biodegradable Alternative to Polyacrylate and Other Currently Used Water Soluble Polymers

Module Description

Author Contact: dheald@siena.edu

Summary

Scale build up, the formation of insoluble inorganic compounds on a surface, can significantly impact a variety of industrial water handling processes. Materials that form complexes with water-soluble cations have proven to be effective antiscalants. Polyacrylate is an extensively used anionic antiscalant and dispersant made by reaction of poly(acrylic acid) with sodium hydroxide. While non-toxic, polyacrylate is not biodegradable and so must be precipitated as sludge and landfilled. This learning module discusses the synthesis of biodegradable, thermal polyaspartates (TPA) as a greener replacement for polyacrylate. TPA is prepared by heating L-aspartic acid to produce polysuccinimide in high yield with only water as a byproduct. Polysuccinimide is subsequently ring opened with sodium hydroxide to give polyaspartate with alpha and beta-linkages.

The Donlar Corporation developed, manufactures, and markets TPA and received the first Presidential Green Chemistry Challenge Award in the small business category in 1996. The module includes a list of seven questions, "Notes to Instructors" and a PowerPoint presentation. Concepts described in this module can be incorporated during a discussion of polymers and polymer chemistry.

Summary prepared July 2005 by Bruce D. Allison, Department of Chemistry at Rose-Hulman Institute of Technology.

Source

Narsavage-Heald, D. Thermal Polyaspartate as a Biodegradable Alternative to Polyacrylate and Other Currently Used Water Soluble Polymers. http://academic.scranton.edu/ faculty/ CANNM1/ polymer/ polymermodule.html (accessed June 2011).

Category Descriptors

Chemistry Concepts
  • Polymerization
Green Chemistry Principles
  • Design for Degradation
  • Design Less Hazardous Chemical Syntheses
  • Design Safer Chemicals and Products
  • Prevent Waste
  • Use Catalysts
  • Use Renewable Feedstocks
Chemistry Subdiscipline
  • Organic Chemistry
  • Polymer Chemistry
Target Audience
  • Colleges/Universities
  • Secondary Schools
Source
  • Internet Sources